5 research outputs found
Quantum Thermodynamic Cycles and quantum heat engines
In order to describe quantum heat engines, here we systematically study
isothermal and isochoric processes for quantum thermodynamic cycles. Based on
these results the quantum versions of both the Carnot heat engine and the Otto
heat engine are defined without ambiguities. We also study the properties of
quantum Carnot and Otto heat engines in comparison with their classical
counterparts. Relations and mappings between these two quantum heat engines are
also investigated by considering their respective quantum thermodynamic
processes. In addition, we discuss the role of Maxwell's demon in quantum
thermodynamic cycles. We find that there is no violation of the second law,
even in the existence of such a demon, when the demon is included correctly as
part of the working substance of the heat engine.Comment: 17 pages, 9 figures, 4 table
Explanation of the Gibbs paradox within the framework of quantum thermodynamics
The issue of the Gibbs paradox is that when considering mixing of two gases
within classical thermodynamics, the entropy of mixing appears to be a
discontinuous function of the difference between the gases: it is finite for
whatever small difference, but vanishes for identical gases. The resolution
offered in the literature, with help of quantum mixing entropy, was later shown
to be unsatisfactory precisely where it sought to resolve the paradox.
Macroscopic thermodynamics, classical or quantum, is unsuitable for explaining
the paradox, since it does not deal explicitly with the difference between the
gases. The proper approach employs quantum thermodynamics, which deals with
finite quantum systems coupled to a large bath and a macroscopic work source.
Within quantum thermodynamics, entropy generally looses its dominant place and
the target of the paradox is naturally shifted to the decrease of the maximally
available work before and after mixing (mixing ergotropy). In contrast to
entropy this is an unambiguous quantity. For almost identical gases the mixing
ergotropy continuously goes to zero, thus resolving the paradox. In this
approach the concept of ``difference between the gases'' gets a clear
operational meaning related to the possibilities of controlling the involved
quantum states. Difficulties which prevent resolutions of the paradox in its
entropic formulation do not arise here. The mixing ergotropy has several
counter-intuitive features. It can increase when less precise operations are
allowed. In the quantum situation (in contrast to the classical one) the mixing
ergotropy can also increase when decreasing the degree of mixing between the
gases, or when decreasing their distinguishability. These points go against a
direct association of physical irreversibility with lack of information.Comment: Published version. New title. 17 pages Revte
The Physics of Maxwell's demon and information
Maxwell's demon was born in 1867 and still thrives in modern physics. He
plays important roles in clarifying the connections between two theories:
thermodynamics and information. Here, we present the history of the demon and a
variety of interesting consequences of the second law of thermodynamics, mainly
in quantum mechanics, but also in the theory of gravity. We also highlight some
of the recent work that explores the role of information, illuminated by
Maxwell's demon, in the arena of quantum information theory.Comment: 24 pages, 13 figures. v2: some refs added, figs improve
Visible and UV coherent Raman spectroscopy of dipicolinic acid
We use time-resolved coherent Raman spectroscopy to obtain molecule-specific signals from dipicolinic acid (DPA), which is a marker molecule for bacterial spores. We use femtosecond laser pulses in both visible and UV spectral regions and compare experimental results with theoretical predictions. By exciting vibrational coherence on more than one mode simultaneously, we observe a quantum beat signal that can be used to extract the parameters of molecular motion in DPA. The signal is enhanced when an UV probe pulse is used, because its frequency is near-resonant to the first excited electronic state of the molecule. The capability for unambiguous identification of DPA molecules will lead to a technique for real-time detection of spores